WebIntroduction Bicyclo[1.1.0]butanes (BCBs 1, Fig. 1a) are a class of hydrocarbons consisting of two cyclopropane rings fused through a common C–C bond.The fused bicyclic structure is highly strained (ring strain energy ∼66 kcal mol −1, more than twice that of cyclopropane), 1 which renders BCBs valuable intermediates in ‘strain release’ chemistry for the synthesis … WebIn organic chemistry, Bredt's rule is an empirical observation that states that a double bond cannot be placed at the bridgehead of a bridged ring system, unless the rings are large enough. The rule is named after Julius Bredt, who first discussed it in 1902 [1] and codified it …
Bridgehead Definition & Meaning - Merriam-Webster
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Building bridges Nature Chemistry
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